α-Trifluoromethyl-Destabilized Cations. A Route to 1-(Trifluoromethyl)tetralins by Trifluoroactolysis of 5-Aryl-1,1,1,-trifluoropentan-2-ols and Derivatives

DOI: 10.1021/jo00239a010

Source and publish data:

Journal of Organic Chemistry p. 754 - 759 (1988)

Update date:2022-08-03

Topics:

Authors:

Bonnet-Delpon, Daniele

Cambillau, Christian

Charpentier-Morize, Micheline

Jacquot, Roland

Mesureur, Dany

Ourevitch, Michele

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Article abstract of DOI:10.1021/jo00239a010

Trifluoroacetolysis of 5-aryl-1,1,1-trifluoropentan-2-ols 1 and their 2-aryl (2) and 2-methyl (3) analogues has been studied in search of a route to 1-(trifluoromethyl)tetralins.The results reflect the relative stabilities of the incipient carbocation int

Full text of DOI:10.1021/jo00239a010

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