A Simple Preparation of N-Protected α-Amino Esters with α,α-Disubstituents from Ethyl Azidoformate and Ketene Silyl Acetals

DOI: 10.1246/cl.1987.1029

Source and publish data:

Chemistry Letters p. 1029 - 1030 (1987)

Update date:2022-08-04

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Authors:

Mitani, Michiharu

Tachizawa, Osamu

Takeuchi, Hiroshi

Koyama, Kikuhiko

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Article abstract of DOI:10.1246/cl.1987.1029

The photolysis of ethyl azidoformate in CH3CN containing ketene silyl acetals afforded N-ethoxycarbonyl α-amino esters with α,α-disubstituents in one step.

Full text of DOI:10.1246/cl.1987.1029

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Product name:Benzeneacetic acid, a-[(ethoxycarbonyl)amino]-a-methyl-, methyl ester

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