A Simple Preparation of N-Protected α-Amino Esters with α,α-Disubstituents from Ethyl Azidoformate and Ketene Silyl Acetals

DOI: 10.1246/cl.1987.1029

Source and publish data:

Chemistry Letters p. 1029 - 1030 (1987)

Update date:2022-08-04

Topics:

Authors:

Mitani, Michiharu

Tachizawa, Osamu

Takeuchi, Hiroshi

Koyama, Kikuhiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.1029

The photolysis of ethyl azidoformate in CH3CN containing ketene silyl acetals afforded N-ethoxycarbonyl α-amino esters with α,α-disubstituents in one step.

Full text of DOI:10.1246/cl.1987.1029

Products guided by the article

Product name:Benzeneacetic acid, a-[(ethoxycarbonyl)amino]-a-methyl-, methyl ester

Cas No:112471-97-3

R&D Labs maybe for 112471-97-3

Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai

Relevant to this article

An amidation/cyclization approach to the synthesis of N-hydroxyquinolinones and their biological evaluation as potential anti-plasmodial, anti-bacterial, and iron(II)-chelating agents

Doi:10.1016/j.bmcl.2014.12.014
(2015)
Addition reactions of chloro- Or iodomethyllithium to imines. Synthesis of enantiopure aziridines and β-chloroamines

Doi:10.1021/jo802596y
(2009)
Intramolecular carbolithiation reactions for the synthesis of 2,4-disubstituted tetrahydro-quinolines: Evaluation of TMEDA and (-)-sparteine as ligands in the stereoselectivity

Doi:10.1021/ol900066c
(2009)
Synthesis, structure, and complexing ability of fluoroalkyl-containing 2,2′-(biphenyl-4,4′-diyldihydrazono)bis(1,3-dicarbonyl) compounds

Doi:10.1134/S107042800712007X
(2007)
A spray-processable, low bandgap, and ambipolar donor - Acceptor conjugatedpolymer

Doi:10.1021/ja809372u
(2009)
Synthesis and antimicrobial activity of sulfur derivatives of quinolinium salts

Doi:10.3390/molecules23010218
(2018)

Article Doi