Tetrahedron Letters p. 5191 - 5192 (1999)
Update date:2022-07-30
Topics:
Siendt, Herve
Tschamber, Theophile
Streith, Jacques
Rhodium/alumina catalysed cis-hydrogenation of the known enol-acetate 7 proceeded quantitatively and with complete stereoselectivity leading to the D-gulose derivative 8. Several reaction steps permitted transformation of 8 into the target D-xylo-imidazolopiperidinose ent-4 molecule, i.e, the enantiomer of the already known imidazolo-sugar 4.
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