New Bonding Mode of Tricyclohexylphosphoniothiocarboxylate (S2CPCy3) as an Eight-electron Donor. Synthesis, Reactivity, and X-Ray Crystal Structure of

DOI: 10.1039/c39870000472

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Journal of the Chemical Society. Chemical communications p. 472 - 474 (1987)

Update date:2022-08-05

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Authors:

Miguel, Daniel

Riera, Victor

Miguel, Jesus A.

Solans, Xavier

Font-Altaba, Manuel

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Article abstract of DOI:10.1039/c39870000472

The reaction of Mn2(CO)10 with the tricyclohexylphosphine-carbon disulphide adduct S2CPCy3 in refluxing toluene affords the dinuclear complex (1) in good yield, the structure of which, determined by X-ray crystallography, shows a new mode of co-ordination of the S2CPCy3 ligand which is bonded to an Mn atom by two sulphur atoms and to the other Mn atom by two sulphur and one carbon atom donating 8 electrons; thermal reactions of (1) with neutral monodentate ligands L yield via CO displacement.

Full text of DOI:10.1039/c39870000472

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