Journal of the Chemical Society. Chemical communications p. 472 - 474 (1987)
Update date:2022-08-05
Topics:
Miguel, Daniel
Riera, Victor
Miguel, Jesus A.
Solans, Xavier
Font-Altaba, Manuel
The reaction of Mn2(CO)10 with the tricyclohexylphosphine-carbon disulphide adduct S2CPCy3 in refluxing toluene affords the dinuclear complex a new mode of co-ordination of the S2CPCy3 ligand which is bonded to an Mn atom by two sulphur atoms and to the other Mn atom by two sulphur and one carbon atom donating 8 electrons; thermal reactions of (1) with neutral monodentate ligands L yield
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