Nickel-Catalyzed Silylolefination of Dithioacetals. A Stereoselective Way to Vinylsilanes

DOI: 10.1021/jo00244a060

Source and publish data:

Journal of Organic Chemistry p. 2129 - 2131 (1988)

Update date:2022-08-04

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Authors:

Ni, Zhi-Jie

Luh, Tien-Yau

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Article abstract of DOI:10.1021/jo00244a060

(E)-Vinylsilanes are synthesized stereoselectively in good yields from dithioacetals and Me3SiCH2MgCl in the presence of a catalytic amount of NiCl2(PPh3)2.

Full text of DOI:10.1021/jo00244a060

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Product name:Silane, trimethyl[[4-[2-(trimethylsilyl)ethenyl]phenyl]methyl]-, (E)-

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Article Doi

Nickel-Catalyzed Silylolefination of Dithioacetals. A Stereoselective Way to Vinylsilanes

DOI: 10.1021/jo00244a060

Source and publish data:

Authors:

Article abstract of DOI:10.1021/jo00244a060

Full text of DOI:10.1021/jo00244a060

Products guided by the article

R&D Labs maybe for 113509-28-7

Relevant to this article

SYNTHESIS OF 4-SUBSTITUTED 1-METHYL(BENZYL)-2,5-DIMETHYL-4-R-AMINOPIPERIDINES

NHC ligands with a secondary pyrimidyl donor for electron-rich palladium(0) complexes

Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.

Stereocontrolled synthesis of β-amino alcohols from lithiated aziridines and boronic esters

From a stannene and quinones to various tin-containing heterocycles