Nickel-Catalyzed Silylolefination of Dithioacetals. A Stereoselective Way to Vinylsilanes

DOI: 10.1021/jo00244a060

Source and publish data:

Journal of Organic Chemistry p. 2129 - 2131 (1988)

Update date:2022-08-04

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Authors:

Ni, Zhi-Jie

Luh, Tien-Yau

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Article abstract of DOI:10.1021/jo00244a060

(E)-Vinylsilanes are synthesized stereoselectively in good yields from dithioacetals and Me3SiCH2MgCl in the presence of a catalytic amount of NiCl2(PPh3)2.

Full text of DOI:10.1021/jo00244a060

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Product name:Silane, trimethyl[[4-[2-(trimethylsilyl)ethenyl]phenyl]methyl]-, (E)-

Cas No:113509-28-7

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