DIASTEREOSELECTION IN TRIMETHYLSILYL TRIFLUOROMETHANESULPHONATE CATALYZED REACTION OF SILYL KETENE ACETALS WITH IMINES

DOI: 10.1016/S0040-4039(00)96501-8

Source and publish data:

Tetrahedron Letters p. 4331 - 4334 (1987)

Update date:2022-07-30

Topics:

Authors:

Guanti, Giuseppe

Narisano, Enrica

Banfi, Luca

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96501-8

The trimethylsilyl trifluoromethanesulphonate catalyzed condensation of silyl ketene acetals with imines afforded β-amino esters with prevalent anti relative diastereoselectivity (up to 100percent).Some anti β-amino esters have been then cyclized to trans

Full text of DOI:10.1016/S0040-4039(00)96501-8

Products guided by the article

Product name:2-Azetidinone, 4-[[(1,1-dimethylethyl)dimethylsilyl]ethynyl]-1-(4-methoxyphenyl)-3-methyl -, trans-

Cas No:114070-48-3

R&D Labs maybe for 114070-48-3

FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Hebei Maison Chemical Co.,Ltd

website:http://www.maisonchem.com.cn

Contact:0086-311-83833777

Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.

Relevant to this article

Nucleosides of 1,4-thiazin-3-one and derivatives as tetrahedral intermediate analogues of enzymes in pyrimidine nucleoside metabolism

Doi:10.1021/jm00403a015
(1988)
Polycyclic Aryl- and Heteroarylpiperazinyl Imides as 5-HT_1A Receptor Ligands and Potential Anxiolytic Agents: Synthesis and Structure-Activity Relationship

Doi:10.1021/jm00402a023
(1988)
Probing specific RNA bulge conformations by modified fluorescent nucleosides

Doi:10.1039/b816768k
(2009)
Complete and Versatile Post-Synthetic Modification on Iron-Triazole Spin Crossover Complexes: A Relevant Material Elaboration Method

Doi:10.1002/ejic.202100090
(2021)
Synthesis of 2-fluoro-2-deoxy-myo-inositol 1,4,5-trisphosphate and scyllo-inositol 1,2,4-trisphosphate, novel analogues of the second messenger myo-inositol 1,4,5-trisphosphate

Doi:10.1016/S0040-4039(00)77615-5
(1993)
2,4-Disubstituted 4-Oxoalkanenitriles and 3-Cyanoalkane-1,5-diones via Michael-Addition of Lithioacetonitrile to 2-(N-Methylanilino)acrylonitrile. A Regioselective Four Component Coupling Reaction

Doi:10.1055/s-1987-28127
(1987)

Article Doi