Complexation of Paraquat and Diquat by a Bismetaphenylene-32-crown-10 Derivative

DOI: 10.1039/c39870001058

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1058 - 1061 (1987)

Update date:2022-08-04

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Authors:

Allwood, Billy L.

Shahriari-Zavareh, Hooshang

Stoddart, J. Fraser

Williams, David J.

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Article abstract of DOI:10.1039/c39870001058

U.v. and 1H n.m.r. spectroscopic studies in solution on the 1:1 complexes both 2 and 2 form with the bismethaphenylene-32-crown-10 derivative (BMP32C10), supported y X-ray crystal structures on the free BMP32C10 and 2*Me2CO, provide further fundamental understanding of the electronic and steric nature of the intermolecular noncovalent interactions that are that are essential to the successful design and synthesis of a molecular receptor for optimal binding of the ²⁺ dication.

Full text of DOI:10.1039/c39870001058

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