Dramatic Steric Distortions and Electronic Demands in 1,3,5-Tris(dialkylamino)-2,4,6-trinitrobenzene: Study of a Severely Warped Benzene

Article abstract of DOI:10.1021/ja00197a066

The static and dynamic stereochemistry of 1,3,5-tris(dialkylamino)-2,4,6-trinitrobenzene is described by a combination of crystallographic, VT-NMR, and semiempirical calculational methods.Crystal data for the N,N-diethyl derivative 1b: C18H30N6O6, M = 426