Synthetic studies toward marine toxic polyethers. 3. Stereocontrol for segment-A1 of okadaic acid by means of oxymercuration and epoxydation

DOI: 10.1016/S0040-4039(00)98902-0

Source and publish data:

Tetrahedron Letters p. 5199 - 5202 (1985)

Update date:2022-07-29

Topics:

Authors:

Isobe Isobe

Ichikawa

Goto Goto

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Article abstract of DOI:10.1016/S0040-4039(00)98902-0

Segment-A₁ of okadaic acid was synthesized from glucose via an acyclic stereocontrol for C-2 by means of oxymercuration. The stereochemistry was proven by comparison with S and R epoxides which were synthesized selectively by chelational and st

Full text of DOI:10.1016/S0040-4039(00)98902-0

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