Journal of Organic Chemistry p. 5464 - 5470 (1988)
Update date:2022-08-02
Topics:
Katagiri, Nobuya
Akatsuka, Hidenori
Haneda, Toru
Kaneko, Chikara
Sera, Akira
β-Ribofuranosylmalonates, prospective synthons for a variety of C-nucleosides, have been synthesized stereoselectively through the high-pressure Diels-Alder reaction of furan with dialkyl (acetoxymethylene)malonate, followed by reductive retrograde aldol C-C bond fission of the diol derived from the adduct.
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