PALLADIUM CATALYZED ALLYLIC C-ALKYLATION OF HIGHLY ACIDIC AND ENOLIC HETEROCYCLIC SUBSTRATES: TETRONIC ACID AND TRIACETIC ACID LACTONE

DOI: 10.1016/S0040-4039(00)80156-2

Source and publish data:

Tetrahedron Letters p. 581 - 584 (1988)

Update date:2022-08-04

Topics:

Authors:

Moreno-Manas, Marcial

Prat, Maria

Ribas, Jordi

Virgili, Albert

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Article abstract of DOI:10.1016/S0040-4039(00)80156-2

Tetronic acid (pK_a 3.76) and triacetic acid lactone (pK_a 4.94) have been alkylated at their active carbon atoms by means of thermodinamically controlled palladium catalyzed allylic alkylations.

Full text of DOI:10.1016/S0040-4039(00)80156-2

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