IODOSYLBENZENE-TRIMETHYLSILYL AZIDE-BORON TRIFLUORIDE ETHERATE: A HIGHLY EFFICIENT SYSTEM FOR DIRECT SYNTHESIS OF ALLYL AZIDES FROM ALLYLSILANES

DOI: 10.1016/S0040-4039(01)91354-1

Source and publish data:

Tetrahedron Letters p. 6289 - 6292 (1987)

Update date:2022-08-03

Topics:

Authors:

Arimoto, Masao

Yamaguchi, Hideo

Fujita, Eiichi

Ochiai, Masahito

Nagao, Yoshimitsu

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Article abstract of DOI:10.1016/S0040-4039(01)91354-1

Simple method for the synthesis of allyl azides from allyltrimethylsilanes utilizing the combination of iodosylbenzene-trimethylsilyl azide-boron trifluoride etherate in dichloromethane was developed.A reaction mechanism involving the allyliodine(III) spe

Full text of DOI:10.1016/S0040-4039(01)91354-1

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