IODOSYLBENZENE-TRIMETHYLSILYL AZIDE-BORON TRIFLUORIDE ETHERATE: A HIGHLY EFFICIENT SYSTEM FOR DIRECT SYNTHESIS OF ALLYL AZIDES FROM ALLYLSILANES

DOI: 10.1016/S0040-4039(01)91354-1

Source and publish data:

Tetrahedron Letters p. 6289 - 6292 (1987)

Update date:2022-08-03

Topics:

Authors:

Arimoto, Masao

Yamaguchi, Hideo

Fujita, Eiichi

Ochiai, Masahito

Nagao, Yoshimitsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)91354-1

Simple method for the synthesis of allyl azides from allyltrimethylsilanes utilizing the combination of iodosylbenzene-trimethylsilyl azide-boron trifluoride etherate in dichloromethane was developed.A reaction mechanism involving the allyliodine(III) spe

Full text of DOI:10.1016/S0040-4039(01)91354-1

Products guided by the article

Product name:3-Heptanone, 5-(acetyloxy)-7-phenyl-1-(trimethylsilyl)-

Cas No:116415-00-0

R&D Labs maybe for 116415-00-0

Jiaozuo Zhongwen Trading Coporation Limited

Contact:--

Address:East Renmin Road
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Li's chemicals

Contact:+86-15850770348

Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China

Relevant to this article

Access to 1,3-oxazine-2,4-diones/1,3-thiazine-2,4-diones: Via organocatalytic CO2/COS incorporation into allenamides

Doi:10.1039/c9ob02398d
(2020)
A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

Doi:10.1021/ol900739x
(2009)
Doi:10.1039/CT9211901425
(1921)
Organometallic chemistry of sulfinic acids. Highly stereo- and regioselective intramolecular hydroplatinations. X-ray crystal structure of (Ph₃P)₂Pt[trans-SO₂CH(CH₃)CH ₂CH(CH₂CH₃)]

Doi:10.1021/om00102a010
(1988)
Bronsted acid or solid acid catalyzed Aza-Diels-Alder reactions of methylenecyclopropanes with ethyl (arylimino)acetates

Doi:10.1002/ejoc.200900050
(2009)
Platelet activating factor antagonists: Synthesis and structure-activity studies of novel PAF analogues modified in the phosphorylcholine moiety

Doi:10.1021/jm00121a012
(1989)

Article Doi