Tetrahedron p. 11935 - 11954 (1998)
Update date:2022-08-04
Topics:
Paterson, Ian
Yeung, Kap-Sun
Watson, Christine
Ward, Richard A.
Wallace, Paul A.
A stereocontrolled synthesis of the C1-C32 seco acid derivative 9 for scytophycin C (1) was completed in 14 steps (18.2% yield, 85% ds) from aldehyde (S)-18. Key steps include: (i) the asymmetric crotylboration of (S)- 18 to give hom
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