Tetrahedron Letters p. 3191 - 3194 (1988)
Update date:2022-07-29
Topics:
Branchaud, Bruce P.
Meier, Mark S.
We report a synthesis of the ammonium salt of the 8-carbon monosaccharide 3-deoxy-D-manno-2-octulosonic acid (KDO) starting from D-mannose.The key C-C bond construction in our synthetic strategy is a novel alkyl cobaloxim mediated radical alkyl-alkenyl cr
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