Journal of Organic Chemistry p. 1607 - 1611 (1989)
Update date:2022-07-30
Topics:
Jones, Michael J.
Moad, Graeme
Rizzardo, Ezio
Solomon, David H.
The relative rates of addition of tert-butoxy radicals to substituted styrenes have been evaluated by means of competition experiments.The data demonstrate that tert-butoxy radicals show electrophilic character (ρ = -0.30).An explanation for the apparently anomalous behavior shown by tert-butoxy radicals in their reactions with fluoro olefins is proposed in terms of the ability of α-fluorine substituents to stabilize the incipient C-O bond.
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Doi:10.1021/jo00269a045
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