Journal of the Chemical Society, Dalton Transactions p. 179 - 184 (1989)
Update date:2022-09-26
Topics:
Tomita, Munetoshi
Matsumoto, Naohide
Akagi, Hisako
Okawa, Hisashi
Kida, Sigeo
Three methal complexes, a quinquedentate sale analogue with a pendant sulphur capable of axial co-ordination, 2-methyl-4-benzylthio-N,N'-butane-1,2-diylbis(salicylideneimine) (H2L), and their structures and Properties were examined with regard to the axial co-ordination of the pendant sulphur.A six-co-ordinate structure with the imidazole and the pendant sulphur at the axial sites was inferred for a distorted square pyramid with the chloride ion at the axial site; the pendant sulphur is not co-ordinated to the metal ion.The co-ordination geometry of a short Mn-O(methanol) bond <2.246(3) Angstroem> and a long Mn-S bond <2.798(1) Angstroem>.The electronic spectrum in dichloromethane was characterized by an absorption near 27.3*103 cm-1, which was tentatively assigned to a charge-transfer transition from the co-ordinated sulphur to the manganese(III) ion.
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