Selective Cis-Trans Isomerization of a Tetraene via an Allene Intermediate: Geometric Isomerism via an sp2 to sp2 Sigmatropic Hydrogen Shift and Kinetic Isotope Effect Studies

DOI: 10.1021/ja00187a032

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Journal of the American Chemical Society p. 1770 - 1773 (1989)

Update date:2022-08-05

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Authors:

Palenzuela, J. Antonio

Elnagar, Hassan Y.

Okamura, William H.

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Article abstract of DOI:10.1021/ja00187a032

A kinetic investigation in the unlabeled and deuterium-labeled series of the <1,5> sigmatropic hydrogen shift of vinylallene 5 to trienes 7 plus 8 and the <1,7> sigmatropic hydrogen shift of dienallene 6 to tetraenes 9 plus 10 has been completed.The resul

Full text of DOI:10.1021/ja00187a032

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