Journal of the Chemical Society. Chemical communications p. 290 - 292 (1983)
Update date:2022-08-02
Topics:
Adlington, Robert M.
Baldwin, Jack E.
Rawlings, Bernard J.
The conversion of (i) an equal mixture of the two isomers of cis-2,3-dideuterio-1-aminocyclopropanecarboxylate or (ii) (+/-)-trans-2,3-dideuterio-1-aminocyclopropanecarboxylate by apple slices gave in both cases a 1:1 mixture of cis- and trans-1,2-dideuterioethylene; in contrast the chemical oxidation (NaOCl) of these substances proceeded with complete retention of configuration to cis-dideuterioethylene and trans-dideuterioethylene, respectively.
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