Rearrangement of Cyclobutenones to 2,5- and 2,6-Dialkylated 1,4-Benzoquinones. Synthesis of O-Methylperezone and O-Methylisoperezone

DOI: 10.1021/jo00270a004

Source and publish data:

Journal of Organic Chemistry p. 2032 - 2034 (1989)

Update date:2022-08-02

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Authors:

Perri, Steven T.

Dyke, Hazel J.

Moore, Harold, W.

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Article abstract of DOI:10.1021/jo00270a004

2,5-Dialkylated benzoquinones have been prepared from 4-alkenyl-4-hydroxycyclobutenones by thermolysis followed by oxidation, while 2,6-dialkylated benzoquinones are available by thermolysis of 4-alkynyl-4-hydroxycyclobutenones.The complementarity of thes

Full text of DOI:10.1021/jo00270a004

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