INSERTION OF ELECTROPHILIC PHOSPHORUS INTO CYCLOPROPANES; A NEW SYNTHESIS OF PHOSPHETANES

DOI: 10.1016/S0040-4039(00)80260-9

Source and publish data:

Tetrahedron Letters p. 1219 - 1222 (1988)

Update date:2022-08-04

Topics:

Authors:

Weissman, Steven A.

Baxter, S. G.

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Article abstract of DOI:10.1016/S0040-4039(00)80260-9

Electrophilic phosphorus reagents such as <(Cl)(i-Pr2N)P>⁺ ^- and PhPCl2/AlCl3 are found to insert into monocyclic cyclopropanes to yield phosphetanes.The utility of this new method is demonstrated by synthesizing the first phosphetanes bearing phenyl substituents at carbon.

Full text of DOI:10.1016/S0040-4039(00)80260-9

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Product name:1-Chloro-1-diisopropylamino-2,2-diphenyl-phosphetanium

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