INSERTION OF ELECTROPHILIC PHOSPHORUS INTO CYCLOPROPANES; A NEW SYNTHESIS OF PHOSPHETANES

DOI: 10.1016/S0040-4039(00)80260-9

Source and publish data:

Tetrahedron Letters p. 1219 - 1222 (1988)

Update date:2022-08-04

Topics:

Authors:

Weissman, Steven A.

Baxter, S. G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80260-9

Electrophilic phosphorus reagents such as <(Cl)(i-Pr2N)P>⁺ ^- and PhPCl2/AlCl3 are found to insert into monocyclic cyclopropanes to yield phosphetanes.The utility of this new method is demonstrated by synthesizing the first phosphetanes bearing phenyl substituents at carbon.

Full text of DOI:10.1016/S0040-4039(00)80260-9

Products guided by the article

Product name:1-Chloro-1-diisopropylamino-2,2-diphenyl-phosphetanium

Cas No:120062-19-3

R&D Labs maybe for 120062-19-3

Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
xi'an taima biological engineering co., ltd.

Contact:+8615619038117

Address:6 No,keji road xi'an city of china

Relevant to this article

Ruthenium alkynyl, carbene and alkenyl complexes containing pendant uracil groups: An investigation into the formation of alkenyl-phosphonio complexes

Doi:10.1039/b912855g
(2009)
Di- And dodeca-mitsunobu reactions on C₆₀ derivatives: Postfunctionalization of fullerene mono- and hexakis-adducts

Doi:10.1002/chem.200902141
(2009)
Re-cyclization of 3-(E)-methyl 3-(4-oxo-4H-chromen-3-yl)acrylate with amines and their potential mechanism

Doi:10.1016/j.tet.2013.08.032
(2013)
Siamese depsipeptides: Constrained bicyclic architectures

Doi:10.1002/anie.200904135
(2009)
Oxidative trifluoromethylation of unactivated olefins: An efficient and practical synthesis of α-trifluoromethyl-substituted ketones

Doi:10.1002/anie.201303576
(2013)
Doi:10.1021/jo01082a613
(1960)

Article Doi