Journal of the Chemical Society. Chemical communications p. 255 - 257 (1988)
Update date:2022-09-26
Topics:
Bradley, Prudence
Johnson, Curtis E.
Eisenberg, Richard
A series of luminescent alkyl complexes of formula IrR(CO)L2(mnt), where mnt = maleonitriledithiolate, R = Me, Et, Pr, and CH2N, and L is a triarylphosphine, have been characterized; photolysis of IrMe(CO)(PPh3)2(mnt) shows that Ir-Me bond homolysis is favoured strongly over CO photo-dissociation.
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Doi:10.1021/ja1084207
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