On the Direct Epoxidation of Glycals: Application of a Reiterative Strategy for the Synthesis of β-Linked Oligosaccharides

DOI: 10.1021/ja00199a028

Source and publish data:

Journal of the American Chemical Society p. 6661 - 6666 (1989)

Update date:2022-08-05

Topics:

Authors:

Halcomb, Randall L.

Danishefsky, Samuel J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00199a028

The use of dimethyldioxirane for the first direct epoxidation of glycals is described.The products of such reactions, 1,2-anhydro sugars, are employed in the stereospecific construction of β-linked oligosaccharides.A key element is the use of glycals with

Full text of DOI:10.1021/ja00199a028

Products guided by the article

Product name:1,2-Anhydro-4,6-O-benzylidene-3-O-(tert-butyldimethylsilyl)-β-D-altropyranose

Cas No:121654-02-2

R&D Labs maybe for 121654-02-2

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu

Relevant to this article

Stereodivergent Mannich reaction of bis(trimethylsilyl)ketene acetals with N-tert -butanesulfinyl imines by Lewis acid or Lewis base activation, a one-pot protocol to obtain chiral β-amino acids

Doi:10.1039/c7ob01853c
(2017)
Calixarene-derived chiral tertiary amine-thiourea organocatalyzed asymmetric Michael additions of acetyl acetone and dimethyl malonate to nitroolefins

Doi:10.1016/j.tetasy.2016.01.004
(2016)
Synthesis of an advanced intermediate bearing two hydroxy groups for (-)-tetrodotoxin and its analogs

Doi:10.1246/bcsj.20090223
(2010)
Synthesis and structure-activity relationship of 1,2,4-triazole-containing diarylpyrazolyl carboxamide as CB1 cannabinoid receptor-ligand

Doi:10.1016/j.bmc.2009.12.040
(2010)
Dibenzopentalenes from B(C₆F₅)₃-induced cyclization reactions of 1,2-bis(phenylethynyl)benzenes

Doi:10.1002/anie.201300871
(2013)
Synthesis of 1,4-Thiazepine Derivatives Having Angiotensin-Converting Enzyme Inhibitory Property

Doi:10.1246/cl.1989.137
(1989)

Article Doi