On the Direct Epoxidation of Glycals: Application of a Reiterative Strategy for the Synthesis of β-Linked Oligosaccharides

DOI: 10.1021/ja00199a028

Source and publish data:

Journal of the American Chemical Society p. 6661 - 6666 (1989)

Update date:2022-08-05

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Authors:

Halcomb, Randall L.

Danishefsky, Samuel J.

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Article abstract of DOI:10.1021/ja00199a028

The use of dimethyldioxirane for the first direct epoxidation of glycals is described.The products of such reactions, 1,2-anhydro sugars, are employed in the stereospecific construction of β-linked oligosaccharides.A key element is the use of glycals with

Full text of DOI:10.1021/ja00199a028

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