Journal of the Chemical Society, Dalton Transactions p. 1531 - 1536 (1989)
Update date:2022-09-26
Topics:
Kadish, Karl M.
Xu, Quan Yun Y.
Maiya, G, Bhaskar
Barbe, Jean-Michel
Guilard, Roger
The spectroscopic characterization and electrochemistry of SnL(X)2 is presented where L is the dianion of tetra-p-tolylporphyrin or tetra-m-tolylporphyrin and X is CIO4-, Br-, Cl-, F-, or OH-.In all cases, electroreduction leads to porphyrin ? anion radicals and dianions which were characterized in tetrahydrofuran by spectroelectrochemistry and e.s.r. spectroscopy.Dissociation of one CIO4- ion from SnL(CIO4)2 occurs before electroreduction of the complex but no dissociation is observed either before or after electroreduction of SnL(F)2 or SnL(OH)2.In contrast, one Br- ion dissociates after the first electron addition to SnL(Br)2 while one Cl- ion dissociates from SnCl(Cl)2 after the second electroreduction of this complex.
View MoreAnhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Shanghai Yuanye Bio-Technology Co., Ltd.
website:http://www.shyuanye.com
Contact:+86-21-61845781
Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Hefei Highzone Fine Chemical S&T CO.,LTD
Contact:86-0551-63663560
Address:room 1801 NO. 24 Shuguang RD.
Contact:86-21 60347964
Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
SICHUAN ZHONGBANG NEW MATERIAL CO., LTD
website:http://www.zhongbangst.com
Contact:86-830-2585019
Address:sichuan,china
Doi:10.3987/COM-09-S(S)80
(2010)Doi:10.1016/j.tet.2010.01.085
(2010)Doi:10.1016/j.tet.2010.02.087
(2010)Doi:10.1002/chem.201901363
(2019)Doi:10.1016/j.jallcom.2008.09.196
(2009)Doi:10.1016/S0277-5387(00)86944-2
(1990)
