DIASTEREOSELECTIVE SYNTHESIS OF β- AND γ2-MUUROLENE: A CARBOCATIONIC PATHWAY FROM MONO- TO SESQUITERPENES

DOI: 10.1016/S0040-4020(01)89792-1

Source and publish data:

Tetrahedron p. 6041 - 6046 (1988)

Update date:2022-07-30

Topics:

Authors:

Azizur-Rahman

Klein, Herbert

Dressel, Juergen

Mayr, Herbert

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Article abstract of DOI:10.1016/S0040-4020(01)89792-1

The Lewis acid catalysed addition of the piperityl chlorides 6 to isoprene yields adduct 7, which undergoes a cis-stereoselective cyclisation to give the diastereoisomeric muurolene monohydrochlorides 8.Treatment with potassium tert-butoxide affords β- an

Full text of DOI:10.1016/S0040-4020(01)89792-1

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