
Tetrahedron Letters p. 4909 - 4912 (1988)
Update date:2022-08-03
Topics:
Rowley, Michael
Kishi, Yoshito
The tricyclic ketone 14, an ophiobolin analogue lacking only the C-ring side chain, was synthesized in optically active form; the key step was the intramolecular NiCl2/CrCl2 mediated coupling of 10 to yield 11.
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