Journal of Organic Chemistry p. 4491 - 4493 (1989)
Update date:2022-08-04
Topics: Stereoselective synthesis
Winkler, Jeffrey D.
Lee, Chih-Shone
Rubo, Lauri
Muller, Cheryl L.
Squattrito, Philip J.
The application of the intramolecular dioxenone photocycloaddition to the efficient synthesis of the tricyclic skeleton of the taxane diterpenes, with complete control of the relative stereochemical relationship between the two six-membered rings (A and C), is described.The first example of C-silylation of a ketone (cyclooctanone B-ring) enolate is reported, and the origins of this remarkable reactivity are discussed.
View MoreContact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Tianjin Derchemist Sci-Tech Co., Ltd.
website:http://www.derchemist.com
Contact:+86-22-58627059
Address:Xinmao Science and Technology Park，Huayuan Industrial Park
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Guangzhou Chemical Reagent Factory
Contact:+86-20-8435 9820 or 8435 7345
Address:Southern Guangzhou, Guangdong, China
Doi:10.1021/jo100562s
(2010)Doi:10.1021/ma100550q
(2010)Doi:10.1016/j.ica.2009.11.006
(2010)Doi:10.1080/10426500902917644
(2010)Doi:10.3390/molecules15064283
(2010)Doi:10.1021/ol100596p
(2010)
