Highly Stereoselective Ring Contraction of Heterocyclic Enamines: Total Synthesis of Perhydrohistrionicotoxin and Its 2,6-Epimer

DOI: 10.1021/jo00279a034

Source and publish data:

Journal of Organic Chemistry p. 4419 - 4425 (1989)

Update date:2022-09-26

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Authors:

Duhamel, Pierre

Kotera, Mitsuharu

Monteil, Thierry

Marabout, Benoit

Davoust, Daniel

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Article abstract of DOI:10.1021/jo00279a034

The total syntheses of perhydrohistrionicotoxin (PHTX) and its 2,6-epimer in which the pentyl group, introduced in the early stages, controls the relative configuration of C6 in a highly stereoselective manner are described.Seven-membered heterocyclic ena

Full text of DOI:10.1021/jo00279a034

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