Journal of Organic Chemistry p. 4419 - 4425 (1989)
Update date:2022-09-26
Topics:
Duhamel, Pierre
Kotera, Mitsuharu
Monteil, Thierry
Marabout, Benoit
Davoust, Daniel
The total syntheses of perhydrohistrionicotoxin (PHTX) and its 2,6-epimer in which the pentyl group, introduced in the early stages, controls the relative configuration of C6 in a highly stereoselective manner are described.Seven-membered heterocyclic ena
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