γ-Silicon Stabilization of Carbonium Ions in Solvolysis. 4. Solvolysis of cis- and trans-3-(Trimethylsilyl)cyclohexyl and -3-tert-Butylcyclohexyl p-Bromobenzenesulfonates

DOI: 10.1021/jo00289a047

Source and publish data:

Journal of Organic Chemistry p. 653 - 661 (1990)

Update date:2022-08-05

Topics: Solvolysis Stabilization Cyclohexyl Trimethylsilyl Tert-butyl Carbonium ions cisand trans-

Authors:

Shiner, V.J.

Ensinger, Mark W.

Kriz, George S.

Halley, Karen A.

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Article abstract of DOI:10.1021/jo00289a047

The solvolyses of cis- and trans-3-(trimethylsilyl)cyclohexyl and -3-tert-butylcyclohexyl p-bromobenzenesulfonates (1-4) have been examined in several ethanol- and trifluoroethanol-water solvent mixtures.The α- and β-deuterium kinetic isotope effects have

Full text of DOI:10.1021/jo00289a047

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