Journal of Organic Chemistry p. 653 - 661 (1990)
Update date:2022-08-05
Topics: Solvolysis Stabilization Cyclohexyl Trimethylsilyl Tert-butyl Carbonium ions cisand trans-
Shiner, V.J.
Ensinger, Mark W.
Kriz, George S.
Halley, Karen A.
The solvolyses of cis- and trans-3-(trimethylsilyl)cyclohexyl and -3-tert-butylcyclohexyl p-bromobenzenesulfonates (1-4) have been examined in several ethanol- and trifluoroethanol-water solvent mixtures.The α- and β-deuterium kinetic isotope effects have
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