Journal of the American Chemical Society p. 8491 - 8493 (1989)
Update date:2022-08-05
Topics:
Le, Nguyet Anh
Jones, Maitland
Bickelhaupt, Friedrich
Wolf, Willem H. de
Photochemically or thermally generated dibromocarbene adds to a variety of 1,2-dimethylenecycloalkanes and to norborndiene to give 1,2 and 1,4 addition products.The ratios of the products of the two addition types match those found from dibromocarbene generated from bromoform.Dibromocarbene is capable of 1,4 addition.
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