Ethyl 3-Trifluoro-2-diazo-propionate as a Potentially Useful CF3-containing Building Block: Preparation and 2-Catalysed Reaction with Nitriles

DOI: 10.1039/c39890000607

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 607 - 608 (1989)

Update date:2022-07-29

Topics: Diazo compound Nitriles Oxazoles

Authors:

Shi, Guoqiang

Xu, Yuanyao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000607

A novel CF3-containing building block, ethyl 3-trifluoro-2-diazo-propionate, was easily prepared and reacted readily with nitriles in the presence of rhodium acetate to afford CF3-substituted oxazoles.

Full text of DOI:10.1039/c39890000607

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₂H₁₅F₃N₂O₅S

Cas No:123220-98-4

R&D Labs maybe for 123220-98-4

Hangzhou Zhenghan Biological Technology Co., Ltd.

Contact:86-571-88781753

Address:liangzhu yuhang hangzhou city
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA

Relevant to this article

One-pot synthesis of α-Aminophosphonates catalyzed by boric acid at room temperature

Doi:10.1002/hc.20577
(2010)
Multicomponent synthesis of dihydropyrano[2,3-c]pyrazoles catalyzed by lipase from Aspergillus niger

Doi:10.1016/j.molcatb.2013.03.015
(2013)
Synthesis and biological evaluation of pyrimidine analogs of antimycobacterial purines

Doi:10.1016/j.bmc.2010.04.035
(2010)
New catalyst for phosphonylation of C=X electrophiles

Doi:10.1080/00397911.2010.542602
(2012)
Formation of α-lithio siloles from silylated 1,4-dilithio-1,3- butadienes: Mechanism and applications

Doi:10.1002/asia.200900287
(2010)
Synthesis, characterization, in vitro and molecular docking studies of new 2,5-dichloro thienyl substituted thiazole derivatives for antimicrobial properties

Doi:10.1016/j.ejmech.2010.03.039
(2010)

Article Doi