Stereoselective Aldol Coupling of Cobalt-Complexed Alkynyl Aldehydes

DOI: 10.1021/jo00284a010

Source and publish data:

Journal of Organic Chemistry p. 5426 - 5428 (1989)

Update date:2022-09-26

Topics:

Authors:

Ju, Jingyue

Reddy, B.R.

Khan, Masood

Nicholas, Kenneth M.

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Article abstract of DOI:10.1021/jo00284a010

Although alkynyl aldehydes undergo crossed aldol condensation with trimethylsilyl enol ethers with little stereoselectivity, their dicobalt hexacarbonyl derivatives react with moderate to excellent syn diastereoselectivity.The selectivity is significantly

Full text of DOI:10.1021/jo00284a010

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