Interglucosyl Attack of Hydroxyl Group to Epoxy Ring of 2A,3A-Anhydro-(2AS)-α-cyclodextrin. Selective Preparation of 3A,2B-Anhydro-α-cyclodextrin

DOI: 10.1246/cl.1999.917

Source and publish data:

Chemistry Letters p. 917 - 920 (1989)

Update date:2022-08-03

Topics:

Authors:

Fujita, Kahee

Tahara, Tsutomu

Sasaki, Hideaki

Egashira, Yoshimitsu

Shingu, Tetsuro

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1999.917

2^A,3^A-Anhydro-(2^AS)-α-cyclodextrin was isomerized exclusively to 3^A,2^B-anhydro-α-cyclodextrin by the reaction with aqueous alkali.This implies the selective and interglucosyl attack of 3^F-OH to the epoxy ring.

Full text of DOI:10.1246/cl.1999.917

Products guided by the article

Product name:(2R,3R,4aR,6R,7S,8S,8aR)-2-((S)-1,2-Dihydroxy-ethyl)-3-((R)-1,2-dihydroxy-ethyl)-6-hydroxymethyl-hexahydro-pyrano[2,3-b][1,4]dioxine-7,8-diol

Cas No:123972-57-6

R&D Labs maybe for 123972-57-6

TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Hebei Tete Trade Co., Ltd.

Contact:86-311-83160559

Address:shijiazhuang

Relevant to this article

Regio- and stereocontrolled functionalization of a seven-membered ring via (cycloheptatriene)iron tricarbonyl

Doi:10.1021/ja00157a033
(1990)
Conjugate addition of aryl nucleophiles to α,β-unsaturated cinnamic acid derivatives containing Evans type chiral auxiliaries

Doi:10.1016/j.tetasy.2016.07.003
(2016)
Synthesis of 1,2,4-triazole-3-thiols and their S-substituted derivatives

Doi:10.1134/S1070428010040184
(2010)
Simple and efficient preparation of 2,5-disubstituted oxazoles via a metal-free-catalyzed cascade cyclization

Doi:10.1021/ol101596s
(2010)
Synthesis of new 2,5-dimethyl pyrrole derivatives from acetonylacetone

Doi:10.1016/j.cclet.2010.03.004
(2010)
A General Approach to the Synthesis of Butanolides: Synthesis of the Sex Pheromone of the Japanese Beetle

Doi:10.1021/jo00290a018
(1990)

Article Doi