Stereoselective Addition of Enol Silanes to Nitro Olefins. A Simple Synthesis of Compounds Related to the Insect Antifeedants Azadiradion and Gedunin.

DOI: 10.1021/jo00291a048

Source and publish data:

Journal of Organic Chemistry p. 1349 - 1354 (1990)

Update date:2022-09-26

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Authors:

Mateos, A. Fernandez

Fuente Blanco, Jesus A. de la

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Article abstract of DOI:10.1021/jo00291a048

The Lewis acid mediated aldol reactions of 1-<(trimethylsilyl)oxy>cyclohexene (2) and 2,6,6-trimethyl-1-<(trimethylsilyl)oxy>cyclohexene (6) with (E)-1-(3-furyl)-2-nitro-1-propene (1) was investigated (Schemes I and II and Chart II).The addition of enol s

Full text of DOI:10.1021/jo00291a048

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