(2+1) CYCLOADDITION OF CHLORO(PHENYLTHIO)CARBENE TO VINYL SILANES. A FACILE SYNTHESIS OF HIGHLY FUNCTIONALIZED CYCLOPROPANES

DOI: 10.1016/S0040-4020(01)80142-3

Source and publish data:

Tetrahedron p. 3163 - 3170 (1989)

Update date:2022-08-03

Topics:

Authors:

Schaumann, Ernst

Friese, Carsten

Adiwidjaja, Gunadi

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Article abstract of DOI:10.1016/S0040-4020(01)80142-3

Vinylsilanes 1d-h react with chloro(phenylthio)carbene 2 to give functionalized silylcyclopropanes 3 with high Z-stereoselectivity.For 3g, the relative configuration was proven by an X-ray structural analysis.Synthetic modifications of 3 include eliminati

Full text of DOI:10.1016/S0040-4020(01)80142-3

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