(2+1) CYCLOADDITION OF CHLORO(PHENYLTHIO)CARBENE TO VINYL SILANES. A FACILE SYNTHESIS OF HIGHLY FUNCTIONALIZED CYCLOPROPANES

DOI: 10.1016/S0040-4020(01)80142-3

Source and publish data:

Tetrahedron p. 3163 - 3170 (1989)

Update date:2022-08-03

Topics:

Authors:

Schaumann, Ernst

Friese, Carsten

Adiwidjaja, Gunadi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80142-3

Vinylsilanes 1d-h react with chloro(phenylthio)carbene 2 to give functionalized silylcyclopropanes 3 with high Z-stereoselectivity.For 3g, the relative configuration was proven by an X-ray structural analysis.Synthetic modifications of 3 include eliminati

Full text of DOI:10.1016/S0040-4020(01)80142-3

Products guided by the article

Product name:1,1-bis(phenylthio)-2-methyl-2-trimethylsilylcyclopropane

Cas No:124306-33-8

R&D Labs maybe for 124306-33-8

WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C

Relevant to this article

Doi:10.1016/S0020-1693(00)90126-9
(1989)
Doi:10.1016/S0040-4039(01)89360-6
(1964)
Influence of the steric effects of the Schiff bases and the hydrogen bonds on the bridging modes of the azide groups: Syntheses and crystal structures of three azide-bridged Schiff base zinc(II) complexes

Doi:10.1016/j.inoche.2009.03.009
(2009)
A convenient method for the kinetic resolution of racemic 2-hydroxyalkanoates using diphenylacetic anhydride (DPHAA) and a chiral acyl-transfer catalyst

Doi:10.1016/j.tetasy.2011.08.018
(2011)
Synthesis and characterization of Zn(II), Cd(II), and Hg(II) alkyl-aryl dithiocarbamate: X-ray crystal structure of [(C₆H₅N(et) CS₂)Hg(C₆H₅N(butyl)CS₂)]

Doi:10.1080/15533171003766717
(2010)
Enantioselective 1,6-conjugate addition to cyclic dienones catalyzed by the Cu-DiPPAM complex

Doi:10.1021/ol1017382
(2010)

Article Doi