(2+1) CYCLOADDITION OF CHLORO(PHENYLTHIO)CARBENE TO VINYL SILANES. A FACILE SYNTHESIS OF HIGHLY FUNCTIONALIZED CYCLOPROPANES

DOI: 10.1016/S0040-4020(01)80142-3

Source and publish data:

Tetrahedron p. 3163 - 3170 (1989)

Update date:2022-08-03

Topics:

Authors:

Schaumann, Ernst

Friese, Carsten

Adiwidjaja, Gunadi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80142-3

Vinylsilanes 1d-h react with chloro(phenylthio)carbene 2 to give functionalized silylcyclopropanes 3 with high Z-stereoselectivity.For 3g, the relative configuration was proven by an X-ray structural analysis.Synthetic modifications of 3 include eliminati

Full text of DOI:10.1016/S0040-4020(01)80142-3

Products guided by the article

Product name:1,1-bis(phenylthio)-2-methyl-2-trimethylsilylcyclopropane

Cas No:124306-33-8

R&D Labs maybe for 124306-33-8

Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Shandong Yubin Chemical CO.,LTD

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County

Relevant to this article

Doi:10.1016/S0020-1693(00)90126-9
(1989)
Doi:10.1016/S0040-4039(01)89360-6
(1964)
Influence of the steric effects of the Schiff bases and the hydrogen bonds on the bridging modes of the azide groups: Syntheses and crystal structures of three azide-bridged Schiff base zinc(II) complexes

Doi:10.1016/j.inoche.2009.03.009
(2009)
A convenient method for the kinetic resolution of racemic 2-hydroxyalkanoates using diphenylacetic anhydride (DPHAA) and a chiral acyl-transfer catalyst

Doi:10.1016/j.tetasy.2011.08.018
(2011)
Synthesis and characterization of Zn(II), Cd(II), and Hg(II) alkyl-aryl dithiocarbamate: X-ray crystal structure of [(C₆H₅N(et) CS₂)Hg(C₆H₅N(butyl)CS₂)]

Doi:10.1080/15533171003766717
(2010)
Enantioselective 1,6-conjugate addition to cyclic dienones catalyzed by the Cu-DiPPAM complex

Doi:10.1021/ol1017382
(2010)

Article Doi