Journal of Organometallic Chemistry p. 103 - 122 (1989)
Update date:2022-08-03
Topics:
Rose-Munch, Francoise
Rose, Eric
Semra, Assia
Bois, Claudette
The study of the regioselectivity of the addition of a nucleophile to chlorotoluenetricarbonylchromium complexes, under cine or tele SNAr conditions, indicated that stabilized carbanions added predominantly to the carbon eclipsed by a Cr-CO bond of the most stable conformer.The conformation of p-chlorotoluenetricarbonylchromium has been studied, in solution by 1H NMR and in the solid state by X-ray crystallography.
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