Reductive carbonylation of cobalt(II) in the presence of diphenylphosphine: synthesis and structure of (PPN) and MeCOCo(CO)2(PPH2H)(PPh2OMe)

DOI: 10.1016/0022-328X(89)87084-6

Source and publish data:

Journal of Organometallic Chemistry p. 141 - 150 (1989)

Update date:2022-08-03

Topics:

Authors:

Vastag, Sandor

Marko, Laszlo

Rheingold, Arnold L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(89)87084-6

Cobalt(II) is reduced to Co(-I) by PPh2H in the presence of CO in MeOH solution containing NaOMe; the complex (PPN) (1) was isolated from the reaction product in 12percent yield.Alkylation of the cobaltate anion with MeI gave after addit

Full text of DOI:10.1016/0022-328X(89)87084-6

Products guided by the article

Product name:Co(CO)3(P(C₆H₅)2OCH₃)^(1-)*(P(C₆H₅)3)2N⁽¹⁺⁾={Co(CO)3(P(C₆H₅)2OCH₃)}(P(C₆H₅)3)2N

Cas No:124643-19-2

R&D Labs maybe for 124643-19-2

Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Chemieliva Pharmaceutical Co., Ltd.

website:http://www.chemieliva.com

Contact:+86-23-67770219

Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province

Relevant to this article

Synthesis and catalytic activity of chiral linker-bridged bis-N-heterocyclic carbene dipalladium complexes

Doi:10.3184/174751918X15293145282582
(2018)
Synthesis, structure and DNA cleavage studies of coumarin analogues of tetrahydroisoquinoline and protoberberine alkaloids

Doi:10.1016/j.ejmech.2010.04.041
(2010)
One-pot sequential N and C arylations: An efficient methodology for the synthesis of trans 4-N,N-diaryl aminostilbenes

Doi:10.1002/anie.200462938
(2005)
Enantioselective organocatalytic Michael addition of aldehydes to trifluoroethylidene malonates

Doi:10.1021/ol101894h
(2010)
Synthesis and antioxidant activity of 3,5-di-tert-butyl-4-hydroxyphenylthiomethyltetraalkylcalix[4]resorcinarenes

Doi:10.1134/S107036321509011X
(2015)
Palladium-catalyzed alkenylation of fluoro-substituted furans via C-H activation to form tetrasubstituted furans

Doi:10.1016/j.tet.2010.08.064
(2010)

Article Doi