Reductive carbonylation of cobalt(II) in the presence of diphenylphosphine: synthesis and structure of (PPN) and MeCOCo(CO)2(PPH2H)(PPh2OMe)

DOI: 10.1016/0022-328X(89)87084-6

Source and publish data:

Journal of Organometallic Chemistry p. 141 - 150 (1989)

Update date:2022-08-03

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Authors:

Vastag, Sandor

Marko, Laszlo

Rheingold, Arnold L.

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Article abstract of DOI:10.1016/0022-328X(89)87084-6

Cobalt(II) is reduced to Co(-I) by PPh2H in the presence of CO in MeOH solution containing NaOMe; the complex (PPN) (1) was isolated from the reaction product in 12percent yield.Alkylation of the cobaltate anion with MeI gave after addit

Full text of DOI:10.1016/0022-328X(89)87084-6

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