FLUORIDE CATALYZED MICHAEL REACTION OF α-ISOCYANOESTERS WITH α,β-UNSATURATED CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(00)72729-8

Source and publish data:

Tetrahedron Letters p. 1257 - 1260 (1989)

Update date:2022-07-29

Topics:

Authors:

Murakami, Masahiro

Hasegawa, Naoki

Tomita, Ikuyoshi

Inouye, Masahiko

Ito, Yoshihiko

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Article abstract of DOI:10.1016/S0040-4039(00)72729-8

The Michael reaction of α-isocyanoesters with α,β-unsaturated carbonyl compounds was efficiently promoted by a catalytic amount of tetrabutylammonium fluoride to produce α-isocyano-δ-ketoesters or silyl ethers of their enols in high yields.

Full text of DOI:10.1016/S0040-4039(00)72729-8

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