Tetrahedron Letters p. 3517 - 3520 (1989)
Update date:2022-09-26
Topics: Regioselectivity Diastereoselectivity Chiral Catalyst Enantioselectivity Rearrangement Stereoselective Claisen Rearrangement Substrate Concerted Mechanism Kinetic Control Thermodynamic Control Tautomerization Vinyl Ether Ketene Pericyclic reaction Transition state Stereocenter Sigmatropic shift
Oehrlein, Reinhold
Jeschke, Rainer
Ernst, Beat
Bellus, Daniel
A new method for the preparation of chiral β-branched, γ,δ-unsaturated thioesters and derivatives is presented, which involves the ketene-Claisen rearrangement of chiral allylthioethers.A novel synthesis of the starting chiral allylthioethers is also desc
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(1993)
