Stereocontrolled synthesis of (+)-methoxyphenylkainic acid and (+)-phenylkainic acid

DOI: 10.1021/ol103131p

Source and publish data:

Organic Letters p. 1089 - 1091 (2011)

Update date:2022-07-31

Topics:

Authors:

Higashi, Takumi

Isobe, Yoichiro

Ouchi, Hitoshi

Suzuki, Hiroto

Okazaki, Yuko

Asakawa, Tomohiro

Furuta, Takumi

Wakimoto, Toshiyuki

Kan, Toshiyuki

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Article abstract of DOI:10.1021/ol103131p

The efficient total syntheses of (+)-methoxyphenylkainic acid (3) and (+)-phenylkainic acid (4) were achieved using a rhodium carbenoid-mediated intermolecular C-H insertion reaction. Complete stereoselective construction of the kainoid skeleton was accom

Full text of DOI:10.1021/ol103131p

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