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ChemComm
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COMMUNICATION
Journal Name
to elucidate the reaction mechanism as well as the effects of bulky
carboxylate ligands are currently underway.
4977.
5
(a) S. I. Gorelsky, D. Lapointe and K. FagDnOoIu: ,10J..1A0m39./CDh0CemC0.1S1o29c.K,
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K. Fagnou, J. Org. Chem., 2010, 75, 1047; (c) B. Liégault, D.
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2009, 74, 1826; (d) O. René, D. Lapointr and K. Fagnou, Org.
Lett., 2009, 11, 4560; (e) L. Ackermann and R. Vicente, R. Born,
Adv. Synth. Catal., 2008, 350, 741; (f) L. Ackermann, A.
Scheme
2 Comparison of steric effect of carboxylic acids between (a)
intramolecular- and (b) intermolecular C(sp2)–H bond arylation
Althammer and S. Fenner, Angew. Chem. Int. Ed., 2009, 48
,
201; (g) D. Zhao, W. Wang, S. Lian, F. Yang, J. Lan and J. You,
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(a) D. Lapointe and K. Fagnou, Chem. Lett., 2010, 39, 1118; (b)
L. Ackermann, Chem. Rev., 2011, 111, 1315.
(a) M. Lafrance, S. I. Gorelsky and K. Fagnou, J. Am. Chem. Soc.,
2007, 129, 14570; (b) M. Lafrance, D. Lapointe and K. Fagnou,
Tetrahedron, 2008, 64, 6015; (c) A. E. Rudenko and B. C.
Thompson, Macromolecules, 2015, 48, 569; (d) T. Fujihara, A.
Yoshida, M. Satou, Y. Tanji, J. Terao and Y. Tsuji, Catal.
Commun., 2016, 84, 71.
6
7
8
9
Y. Tanji, N. Mitsutake, T. Fujihara and Y. Tsuji, Angew. Chem.
Int. Ed., 2018, 57, 10314.
See ESI for detail.
10 (a) S. Liu and L. G. Pedersen, J. Phys. Chem. A, 2009, 113, 3648;
(b) M. Virant, S. D. T. Talian, Č. Podlipnik and B. Hribar-Lee,
Acta. Chim. Slov., 2017, 64, 560.
11 pKa values of 1a-l:
1a (5.03)12 1b (5.37), 1c (4.76),12 1d
This work was supported by JSPS KAKENHI Grant Number
17H03096 in Grant-in-Aid for Scientific Research (B) from MEXT,
Japan (Y. Tsuji). T. Fujihara acknowledged JSPS KAKENHI Grant
Number 18H04257 in Precisely Designed Catalysts with
Customized Scaffolding from MEXT, Japan. Y. Tanji is grateful to
a Research Fellowship from JSPS for Young Scientists.
(4.85),12 1e (4.84),12 1f (4.91), 1g (5.50), 1h (5.35), 1i (5.26), 1j
(5.35), 1k (5.39), 1l (5.11), 1m (5.40).
12 Handbook of Chemistry and Physics, 87th ed.; D. R. Lide, Ed.;
CRC Press: Boca Raton, 2006; 8.
13 M. Gómez-Gallego and M. A. Sierra, Chem. Rev., 2011, 111
,
4857.
Conflicts of interest
There are no conflicts to declare.
Notes and references
1
For reviews, see: (a) J. Yamaguchi, A. D. Yamaguchi and K.
Itami, Angew. Chem. Int. Ed., 2012, 51, 8960; (b) J. F. Hartwig,
J. Am. Chem. Soc., 2016, 138, 2. (c) Y. Minami and T. Hiyama,
Chem. Lett., 2018, 47, 1.
2
For reviews, see: (a) X. Chen, K. M. Engle, D.-H. Wang and J.-
Q. Yu, Angew. Chem. Int. Ed., 2009, 48, 5094; (b) Y. Kuninobu
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Lautens, Nat. Chem., 2015,
T. Dalton and F. Glorius, Angew. Chem. Int. Ed., 2018, 57, 2296.
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,
16496; (b) Y. Tan and J. F. Hartwig, J. Am. Chem. Soc., 2011,
133, 3308.
(a) M. Lafrance, C. N. Rowley, T. K. Woo and K. Fagnou, J. Am.
Chem. Soc., 2006, 128, 8754; (b) L.-C. Campeau, D. R. Stuart,
J.-P. Leclerc, M. Bertrand-Laperle, E. Villemure, H.-Y. Sun, S.
Lasserre, N. Guimond, M. Lecavallier and K. Fagnou, J. Am.
Chem. Soc., 2009, 131, 3291; (c) L.-C. Campeau, M. Bertrand-
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Fagnou, Org. Lett., 2009, 11, 1357; (e) L. Caron, L.-C. Campeau
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4 | J. Name., 2012, 00, 1-3
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