Fluorination Reactions with HF/THF Medium Solvolysis of N-Tosyl-O-Phenylhydroxylamine

DOI: 10.1016/S0040-4039(01)80545-1

Source and publish data:

Tetrahedron Letters p. 4929 - 4930 (1989)

Update date:2022-09-26

Topics:

Authors:

Dolbier, William R.

Celewicz, Lech

Ohnishi, Keiichi

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Article abstract of DOI:10.1016/S0040-4039(01)80545-1

Solvolysis of N-tosyl-O-phenylhydroxylamine in HF/THF leads to regiospecific formation of p-fluorophenol via umpolung strategy which induces nucleophilic aromatic fluorine/hydrogen substitution.

Full text of DOI:10.1016/S0040-4039(01)80545-1

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