Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. Synthesis and Reactions of the cis- and trans-Oxides Derived from 4-(Benzyloxy)cyclohexene

DOI: 10.1021/jo00301a011

Source and publish data:

Journal of Organic Chemistry p. 4265 - 4272 (1990)

Update date:2022-08-05

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Authors:

Chini, Marco

Crotti, Paolo

Flippin, Lee A.

Macchia, Franco

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Article abstract of DOI:10.1021/jo00301a011

The synthesis and reactions of diastereomeric epoxides cis-1 and trans-2 with heteronucleophiles were carried out in order to probe the effect of remote polar functionality on the regioselectivity of nucleophilic addition to the epoxide ring.The reaction

Full text of DOI:10.1021/jo00301a011

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