Bulletin of the Chemical Society of Japan p. 2010 - 2017 (1990)
Update date:2022-08-05
Topics: Efficient Syntheses Organic synthesis Experimental Potassium fluoride
Suzuki, Hiroshi
Yazawa, Naoto
Yoshida, Yasuo
Furusawa, Osamu
Kimura, Yoshikazu
Tetraphenylphosphonium bromide was found to be a suitable catalyst for the reaction of m-nitroaryl derivatives carrying cyano, nitro, chlorocarbonyl, trifluoromethyl, and chlorosulfonyl groups with potassium fluoride in the presence of a stoichiometric amount of phthaloyl dichloride, giving the corresponding m-fluoro aromatic derivatives in good yields.The catalyst was also found to be efficient for the fluorodesulfonylation of m-(fluorosulfonyl)aryl derivatives to afford m-fluoro arenes by the use of a reaction-distillation technique.
View MoreContact:+852 83038667
Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
Beijing Apis Biotechnology Co., Ltd.
Contact:86-010-67856775-8551
Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Contact:+86-21-6856-1349 523-87676172
Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Lonzeal Pharmaceuticals Co., Ltd.
website:http://www.lonzeal.com
Contact:+86-13381011962
Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Doi:10.1002/anie.201006084
(2011)Doi:10.1246/bcsj.63.935
(1990)Doi:10.1021/jp112401k
(2011)Doi:10.1021/jm00172a020
(1990)Doi:10.1002/chem.201500519
(2015)Doi:10.1016/j.bmc.2010.12.053
(2011)
