Preparation of Chiral Inducers Having the Bicycloheptane Framework. Assignment of Diastereomer Configuration by NMR and Comparsion of Calculated and Observed Coupling Constants

Article abstract of DOI:10.1021/jo00001a006

Several bicyclo<3.1.1> compounds have been prepared for possible uses in asymmetric synthesis, including 10-phenyl-α-pinene and the diastereomeric (1S,2S,5S)-10-phenylmyrtanols.The geometry and NMR properties of bicyclo<3.1.1> compounds have been investig