
Tetrahedron p. 103 - 112 (1990)
Update date:2022-08-03
Topics: Synthesize Chemical Reaction Experimental method Fully functionalized
Friesen, Richard W.
Danishefsky, Samuel J.
Synthetic routes to the fully functionalized α-linked disaccharides 19 21 and 25 are described starting from a common intermediate the iodo acetate 15. This substance was in turn prepared via a haloetherification reaction between the allal derivative 13 the galactose alcohol 14 and an "iodonium" equivalent.
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