Tetrahedron Letters p. 2069 - 2072 (1990)
Update date:2022-07-29
Topics:
Clerici
Porta
Free-radical decomposition of arene-diazonium salts 1, catalyzed by aqueous TiCl3, in the presence of aldehydes 2 and anilines 3 leads to secondary amines 4. A mechanism is proposed, according to which the aryl radical adds to the C-atom of the intermediate protonated imine.
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