Facile Elimination of Ethanethiol in the Reaction of α-Hydroxy-β-bis(ethylthio)acetals with Copper(I) Chloride in Dimethylformamide

DOI: 10.1055/s-1990-26960

Source and publish data:

Synthesis p. 618 - 620 (1990)

Update date:2022-08-05

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Authors:

Paryzek, Zdzislaw

Martynow, Jacek

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Article abstract of DOI:10.1055/s-1990-26960

Bis(ethylthio)acetals possessing a hydroxy group in the α-position eliminate, upon reaction with copper(I) chloride in dimethylformamide, cleanly and quantitatively one molecule of ethanethiol with the formation of substituted ethyl vinyl sulfides.

Full text of DOI:10.1055/s-1990-26960

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