Russian Chemical Bulletin p. 522 - 527 (1993)
Update date:2022-09-26
Topics:
Radul, O. M.
Krimer, M. Z.
Rebrova, O. N.
Biyushkin, V. N.
Feofanova, I. V.
Panasenko, A. A.
The rearrangement of enol acylates of aryl 1H-1,2,4-triazol-1-ylmethyl ketones at 140-150 deg C in acetic anhydride is studied.The migration of the acyl group to the C(5) atom of the heterocycle is found to be intramolecular.The characteristics of the original and final products are presented.X-ray structural studies of the enol acetates of 2,4-dichlorophenyl 1H-1,2,4-triazol-1-ylmethyl ketone and 2,4-dichlorophenyl 5-acetyl-1H-1,2,4-triazol-1-ylmethyl ketone are carried out.
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Doi:10.1016/S0040-4020(01)81526-X
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