Comparative reactivity of isoelectronic nitrido, methylimido, and oxo complexes of osmium(VI)

DOI: 10.1021/ja00179a022

Source and publish data:

Journal of the American Chemical Society p. 8369 - 8378 (1990)

Update date:2022-09-26

Topics: Reactivity Complexes Oxo Comparative reactivity Isoelectronic

Authors:

Marshman, Robert W.

Shapley, Patricia A.

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Article abstract of DOI:10.1021/ja00179a022

The structures, physical properties, and reaction chemistry of isoelectronic alkyl complexes of osmium(VI) are compared. The three, five-coordinate alkyl complexes [NBuⁿ₄][Os(N)(CH₂SiMe₃) ₄], Os(NMe)(

Full text of DOI:10.1021/ja00179a022

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