Neuartige basische Liganden fuer die homogenkatalytische Methanolcarbonylierung XXX. (Dioxanylmethyl)phosphanrhodium-Komplexe als Modellverbindungen in der Methanolcarbonylierung

DOI: 10.1016/0022-328X(90)85069-B

Source and publish data:

Journal of Organometallic Chemistry p. C37 - C40 (1990)

Update date:2022-08-03

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Authors:

Linder, Ekkehard

Glaser, Erhard

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Article abstract of DOI:10.1016/0022-328X(90)85069-B

The cationic complex O)2> (3) is obtained from <μ-ClRh(COD)>2 (1), NaPF6/acetone and the ligand Me3Si(CH2)3P(Ph)CH2C4H7O2 (2).In 3 COD is displaced by CO to form O)2Rh(CO)3> (4). 4 readily eliminates carbon monoxide to f

Full text of DOI:10.1016/0022-328X(90)85069-B

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